A near-field optical method for probing liquid–liquid interfaces

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Author(s) De Serio, M., Bader, Arjen N., Heule, Martin, Zenobi, Renato, Deckert, Volker
Publication Type Journal Items, Publication Status: Published
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Title A near-field optical method for probing liquid–liquid interfaces
Author(s) De Serio, M.
Bader, Arjen N.
Heule, Martin
Zenobi, Renato
Deckert, Volker
Journal or Series Title Chemical physics letters
Volume Number 380
Issue Number 1-2
Start Page 47
End Page 53
ISSN 0009-2614
Publisher Elsevier
Publication Place Amsterdam
Publication Date 2003-10
Abstract A high resolution method to study the interface between two immiscible liquids is presented. The technique is based on the combination of a near-field optical probe and Raman spectroscopy. This combination brings together high local resolution in tip direction and the capability for molecular analysis at the interface. First trans-phase boundary Raman profiles on the p-xylene/ethylene glycol system measured with a spatial resolution of 1 mum are presented. Changes in the Raman bands due to the influence of the phase boundary extend as far as 10 mum from the phase boundary itself. Studies with coated and uncoated near-field probes demonstrate the important role of the optical near field in the experiments.
DOI 10.1016/j.cplett.2003.08.091
Document Type Article
Publication Status Published
Language English
NEBIS System Number 000033700
Source Database ID WOS-000186015000008
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  author = "De Serio, M. and Bader, Arjen N. and Heule, Martin and Zenobi, Renato and Deckert, Volker",
  title = "{A} near-field optical method for probing liquid{\textendash}liquid interfaces",
  journal = "Chemical physics letters",
  year = 2003,
  volume = "380",
  number = "1-2",
  pages = "47--53",
  month = oct,

E-Citations record created: Mon, 03 Sep 2012, 15:44:58 CET