Probing the mechanisms of ambient ionization by laser-induced fluorescence spectroscopy

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Author(s) Frankevich, Vladimir E., Nieckarz, Robert J., Sagulenko, Pavel N., Barylyuk, Konstantin V., Zenobi, Renato, Levitsky, Lev I., Agapov, Alexander Y., Perlova, Tatyana Y., Gorshkov, Michael V., Tarasova, Irina A.
Publication Type Journal Items, Publication Status: Published
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Title Probing the mechanisms of ambient ionization by laser-induced fluorescence spectroscopy
Author(s) Frankevich, Vladimir E.
Nieckarz, Robert J.
Sagulenko, Pavel N.
Barylyuk, Konstantin V.
Zenobi, Renato
Levitsky, Lev I.
Agapov, Alexander Y.
Perlova, Tatyana Y.
Gorshkov, Michael V.
Tarasova, Irina A.
Journal or Series Title Rapid communications in mass spectrometry : RCM
Volume Number 26
Issue Number 13
Start Page 1567
End Page 1572
ISSN 0951-4198
Publisher Wiley
Publication Place London
Publication Date 2012-07
Abstract The ionization mechanisms of several atmospheric pressure ion sources based on desorption and ionization of samples deposited on a surface were studied. Home-built desorption electrospray ionization (DESI), laserspray ionization (LSI), and atmospheric pressure matrix-assisted laser desorption/ionization (AP-MALDI) sources were characterized using low-molecular-weight compounds, in particular fluorescent dyes. Detection of the desorbed and ionized species was performed by laser-induced fluorescence and ion cyclotron resonance mass spectrometry. The dependences of the signal intensities on various experimental parameters were studied. The data obtained reveals common features, such as formation of solvated species and clusters in the ionization processes, in all of the techniques considered.
DOI 10.1002/rcm.6264
Additional Notes Received 6 March 2012, Revised 26 April 2012, Accepted 26 April 2012
Document Type Article
Publication Status Published
Language English
Assigned Organisational Unit(s) 03430
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NEBIS System Number 000038989
Source Database ID WOS-000304438500007
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  author = "Frankevich, Vladimir E. and Nieckarz, Robert J. and Sagulenko, Pavel N. and Barylyuk, Konstantin V. and Zenobi, Renato and Levitsky, Lev I. and Agapov, Alexander Y. and Perlova, Tatyana Y. and Gorshkov, Michael V. and Tarasova, Irina A.",
  title = "{P}robing the mechanisms of ambient ionization by laser-induced fluorescence spectroscopy",
  journal = "Rapid communications in mass spectrometry : RCM",
  year = 2012,
  volume = "26",
  number = "13",
  pages = "1567--1572",
  month = jul,

E-Citations record created: Mon, 18 Jun 2012, 16:05:23 CET